Atomic structure of sodium iron phosphate glasses

نویسندگان

چکیده

The atomic structure of a series sodium iron phosphate glasses is studied using different experimental techniques: X-ray and neutron diffraction (ND), infrared spectroscopy, extended absorption fine (EXAFS), near-edge (XANES). Detailed information about the pair correlations obtained. high resolution ND in real space resolves two P–O distances at 1.48 ? 1.59 as expected. All are found to consist tetrahedral network with metaphosphate chains pyrophosphate units, every unit have or three nonbridging oxygen (NBO) links available coordinate Na Fe cations. Fe–O coordination number these decrease from 5.7 4.8 increasing content, whereas approximately 5 detected for all samples.

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ژورنال

عنوان ژورنال: International Journal of Applied Glass Science

سال: 2021

ISSN: ['2041-1294', '2041-1286']

DOI: https://doi.org/10.1111/ijag.15865